The rock formations in the Chiricahuas are Rhyolite.

Rhyolite is an igneous, volcanic (extrusive) rock, of felsic (silicon-rich) composition (typically >69% SiO2). It may have any texture from aphanitic to porphyritic. The mineral assemblage is usually quartz, alkali feldspar and plagioclase (in a ratio > 1:2). Biotite and hornblende are common accessory minerals.

Rhyolite can be considered as the extrusive equivalent to the plutonic granite rock, and consequently, outcroppings of it often bear a resemblance to granite. Due to their high content of silica and low iron and magnesium contents, rhyolite melts are highly polymerized and form highly viscous lavas. They can also occur as breccias or in volcanic plugs and dykes. Rhyolites that cool too quickly to grow crystals form a natural glass or vitrophyre, also called obsidian. Slower cooling forms microscopic crystals in the lava and results in textures such as flow foliations, spherulitic, nodular, and lithophysal structures. Some rhyolite is highly vesicular pumice. Many eruptions of rhyolite are highly explosive and the deposits may consist of fallout tephra or of ignimbrites.